| Common Name: | HEAVY DUTY DEGREASER 03095, 03095T |
| Manufacturer: | CRC |
| MSDS Revision Date: | 5/19/2014 |
| MSDS Format: | GHS-US |
| Grainger Item Number(s): | 1D265, 1HBL3 |
| Manufacturer Model Number(s): |
MSDS Table of Contents
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CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: HEAVY DUTY DEGREASER
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 03095, 03095T
RECOMMENDED USE: GENERAL PURPOSE DEGREASER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
GASES UNDER PRESSURE: COMPRESSED GAS
HEALTH HAZARDS:
ACUTE TOXICITY, INHALATION: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2B
CARCINOGENICITY: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 2
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. CAUSES SKIN IRRITATION.
CAUSES EYE IRRITATION. HARMFUL IF INHALED. MAY CAUSE DROWSINESS OR
DIZZINESS. MAY CAUSE CANCER BY INHALATION OR INGESTION. TOXIC TO AQUATIC
LIFE. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT PUNCTURE OR INCINERATE
CONTAINER. DO NOT EXPOSE TO HEAT OR STORE AT TEMPERATURES ABOVE
49 DEG. C/120 DEG. F. USE WITH ADEQUATE VENTILATION. OPEN DOORS AND
WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR SUPPLY DURING USE AND
WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY SYMPTOMS LISTED ON THIS
LABEL, INCREASE VENTILATION OR LEAVE THE AREA. AVOID BREATHING MIST OR
VAPOR. AVOID BREATHING GAS. WASH THOROUGHLY AFTER HANDLING. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE
REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION. COLLECT SPILLAGE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. STORE LOCKED UP. EXPOSURE TO HIGH
TEMPERATURE MAY CAUSE CAN TO BURST.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION:
11.13% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE HAZARDS TO
THE AQUATIC ENVIRONMENT. 3.4% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF
UNKNOWN LONG-TERM HAZARDS TO THE AQUATIC ENVIRONMENT.
WHEN EXPOSED TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO
HARMFUL OR FATAL CORROSIVE GASES SUCH AS HYDROGEN FLUORIDE, HYDROGEN
CHLORIDE AND POSSIBLY PHOSGENE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
TETRACHLOROETHYLENE PERCHLOROETHYLENE 127-18-4 80 - 90
COZOL(R*) 210 PROPRIETARY 5 - 10
CARBON DIOXIDE 124-38-9 1 - 3
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. CALL A POISON CENTER
OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT: RINSE SKIN WITH WATER/SHOWER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET
MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
IF INGESTION OF A LARGE AMOUNT DOES OCCUR, CALL A POISON CONTROL CENTER
IMMEDIATELY. RINSE MOUTH. DO NOT INDUCE VOMITING.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
IRRITATION OF EYES AND MUCOUS MEMBRANES. IRRITATION OF NOSE AND THROAT.
EXPOSED INDIVIDUALS MAY EXPERIENCE EYE TEARING, REDNESS, AND DISCOMFORT.
SYMPTOMS OF OVEREXPOSURE MAY BE HEADACHE, DIZZINESS, TIREDNESS, NAUSEA AND
VOMITING. MAY CAUSE REDNESS AND PAIN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
WARM. KEEP VICTIM UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. ENSURE THAT MEDICAL PERSONNEL ARE AWARE
OF THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. WHEN EXPOSED TO EXTREME HEAT OR HOT SURFACES,
VAPORS MAY DECOMPOSE TO HARMFUL OR FATAL CORROSIVE GASES SUCH AS HYDROGEN
FLUORIDE, HYDROGEN CHLORIDE AND POSSIBLY PHOSGENE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO
SO WITHOUT RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR
PRESSURE BUILD UP.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. WEAR APPROPRIATE PROTECTIVE EQUIPMENT
AND CLOTHING DURING CLEAN-UP. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED
MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID
INHALATION OF VAPORS AND SPRAY MISTS. AVOID BREATHING GAS. ENSURE ADEQUATE
VENTILATION. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES
CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. THIS MATERIAL IS CLASSIFIED AS A WATER POLLUTANT UNDER
THE CLEAN WATER ACT AND SHOULD BE PREVENTED FROM CONTAMINATING SOIL OR FROM
ENTERING SEWAGE AND DRAINAGE SYSTEMS WHICH LEAD TO WATERWAYS. STOP THE FLOW
OF MATERIAL, IF THIS IS WITHOUT RISK. COLLECT SPILLAGE. WIPE UP WITH
ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE
RESIDUAL CONTAMINATION. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. CONTACT LOCAL AUTHORITIES IN CASE OF
SPILLAGE TO DRAIN/AQUATIC ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE
IF SAFE TO DO SO. DO NOT CONTAMINATE WATER. AVOID DISCHARGE INTO DRAINS,
WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE
IS THOROUGHLY DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. USE
CAUTION AROUND ENERGIZED EQUIPMENT. THE METAL CONTAINER WILL CONDUCT
ELECTRICITY IF IT CONTACTS A LIVE SOURCE. THIS MAY RESULT IN INJURY TO THE
USER FROM ELECTRICAL SHOCK AND/OR FLASH FIRE. AVOID INHALATION OF VAPORS
AND SPRAY MISTS. AVOID BREATHING GAS. AVOID CONTACT WITH EYES, SKIN, AND
CLOTHING. AVOID PROLONGED EXPOSURE. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. SHOULD BE HANDLED IN CLOSED SYSTEMS, IF POSSIBLE.
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. OBSERVE GOOD INDUSTRIAL
HYGIENE PRACTICES. AVOID RELEASE TO THE ENVIRONMENT. DO NOT EMPTY INTO
DRAINS. FOR PRODUCT USAGE INSTRUCTIONS, PLEASE SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 1 AEROSOL.
CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE AT TEMPERATURES
ABOVE 120 DEG. F/49 DEG. C AS CAN MAY BURST. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES OF
IGNITION. STORE IN A WELL-VENTILATED PLACE. STORE AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
CARBON DIOXIDE PEL 9000 MG/M3
(CAS 124-38-9) 5000 PPM
TRANS-1,2-DICHLOROETHYLENE PEL 790 MG/M3
(CAS 156-60-5) 200 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TETRACHLOROETHYLENE CEILING 200 PPM
(CAS 127-18-4) TWA 100 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
CARBON DIOXIDE STEL 30000 PPM
(CAS 124-38-9) TWA 5000 PPM
TETRACHLOROETHYLENE STEL 100 PPM
(CAS 127-18-4) TWA 25 PPM
TRANS-1,2-DICHLOROETHYLENE TWA 200 PPM
(CAS 156-60-5)
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
CARBON DIOXIDE STEL 54000 MG/M3
(CAS 124-38-9) 30000 PPM
TWA 9000 MG/M3
5000 PPM
TRANS-1,2-DICHLOROETHYLENE TWA 790 MG/M3
(CAS 156-60-5) 200 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING
TIME
TETRACHLOROETHYLENE 0.5 MG/L TETRACHLOROETHYLENE BLOOD *
(CAS 127-18-4)
3 PPM TETRACHLOROETHYLENE END-EXHALED *
AIR
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - MINNESOTA HAZ SUBS SKIN DESIGNATION APPLIES
TETRACHLOROETHYLENE (CAS 127-18-4) SKIN DESIGNATION APPLIES.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO
AN ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: VITON(R*). POLYVINYL ALCOHOL (PVA).
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON
IS RECOMMENDED.
RESPIRATORY PROTECTION:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA). AIR
MONITORING IS NEEDED TO DETERMINE ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: AEROSOL.
COLOR: COLORLESS.
ODOR: SOLVENT.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -112 DEG. F (-80 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE:
119.7 DEG. F (48.7 DEG. C) ESTIMATED
FLASH POINT: NONE (TAG CLOSED CUP)
EVAPORATION RATE: FAST.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 6.7% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 18% ESTIMATED
VAPOR PRESSURE: 1443.6 HPA ESTIMATED
VAPOR DENSITY: >4 (AIR = 1)
RELATIVE DENSITY: 1.58
SOLUBILITY (WATER): SLIGHT.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 860 DEG. F (460 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY (KINEMATIC): NOT AVAILABLE.
PERCENT VOLATILE: 97.6% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
HEAT, FLAMES AND SPARKS. CONTACT WITH INCOMPATIBLE MATERIALS. WHEN EXPOSED
TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO HARMFUL OR FATAL
CORROSIVE GASES SUCH AS HYDROGEN FLUORIDE, HYDROGEN CHLORIDE AND POSSIBLY
PHOSGENE.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
HYDROGEN CHLORIDE. HYDROGEN FLUORIDE. PHOSGENE. CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION:
SINGLE DOSE ORAL TOXICITY IS CONSIDERED TO BE EXTREMELY LOW. SWALLOWING
LARGE AMOUNTS MAY CAUSE INJURY IF ASPIRATED INTO THE LUNGS. THIS MAY BE
RAPIDLY ABSORBED THROUGH THE LUNGS AND RESULT IN INJURY TO OTHER BODY
SYSTEMS.
INHALATION:
HARMFUL IF INHALED. SYMPTOMS OF OVEREXPOSURE MAY BE HEADACHE, DIZZINESS,
TIREDNESS, NAUSEA AND VOMITING.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES EYE IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
IRRITATION OF NOSE AND THROAT. IRRITATION OF EYES AND MUCOUS MEMBRANES.
MAY CAUSE REDNESS AND PAIN. EXPOSED INDIVIDUALS MAY EXPERIENCE EYE TEARING,
REDNESS, AND DISCOMFORT. SYMPTOMS OF OVEREXPOSURE MAY BE HEADACHE,
DIZZINESS, TIREDNESS, NAUSEA AND VOMITING.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: HARMFUL IF INHALED. NARCOTIC EFFECTS.
PRODUCT SPECIES TEST RESULTS
HEAVY DUTY DEGREASER:
ACUTE:
DERMAL:
LD50 RABBIT 3464.3928 MG/KG ESTIMATED
INHALATION:
LC50 RAT 5900.6211 MG/L, 4 HOURS ESTIMATED
4533.9824 PPM, 4 HOURS ESTIMATED
ORAL:
LD50 RAT 2518.0356 MG/KG ESTIMATED
SUBCHRONIC:
INHALATION:
LC50 RAT 51759.8359 PPM, 90 DAYS ESTIMATED
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES EYE IRRITATION.
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: MAY CAUSE CANCER.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
TETRACHLOROETHYLENE (CAS 127-18-4): 2A PROBABLY CARCINOGENIC TO HUMANS.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS:
TETRACHLOROETHYLENE (CAS 127-18-4):
REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. MAY BE
AN ASPIRATION HAZARD.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. ACCUMULATION IN AQUATIC
ORGANISMS IS EXPECTED.
PRODUCT SPECIES TEST RESULTS
HEAVY DUTY DEGREASER:
AQUATIC:
FISH LC50 FISH 21.5469 MG/L, 96 HOURS ESTIMATED
ACUTE:
CRUSTACEA EC50 DAPHNIA 499.3621 MG/L, 48 HOURS ESTIMATED
COMPONENTS SPECIES TEST RESULTS
TETRACHLOROETHYLENE (CAS 127-18-4):
AQUATIC:
FISH LC50 RAINBOW TROUT, 4.73 - 5.27 MG/L, 96 HOURS
DONALDSON TROUT
(ONCORHYNCHUS MYKISS)
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
TETRACHLOROETHYLENE: 2.88
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION,
PHOTOCHEMICAL OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL
WARMING POTENTIAL) ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL OF WASTE FROM RESIDUES / UNUSED PRODUCTS:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE.
EMPTY CONTAINER CAN BE RECYCLED. CONSULT AUTHORITIES BEFORE DISPOSAL.
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR CRUSH. DO NOT ALLOW
THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE
PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER. DISPOSE IN
ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
D039: WASTE TETRACHLOROETHYLENE
F001:
WASTE TETRACHLOROETHYLENE - SPENT HALOGENATED SOLVENT USED IN DEGREASING
F002: WASTE TETRACHLOROETHYLENE - SPENT HALOGENATED SOLVENT
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME:
AEROSOLS, POISON, LIMITED QUANTITY, MARINE POLLUTANT
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.2
SUBSIDIARY RISK: 6.1(PGIII)
LABEL(S): 2.2, 6.1
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: NOT AVAILABLE.
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME:
AEROSOLS, NON-FLAMMABLE, CONTAINING SUBSTANCES IN DIVISION 6.1, PACKING
GROUP III, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.2
SUBSIDIARY RISK: 6.1(PGIII)
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS: NO.
ERG CODE: 2P
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED.
CARGO AIRCRAFT ONLY: ALLOWED.
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, MARINE POLLUTANT
TRANSPORT HAZARD CLASS(ES):
CLASS: 2
SUBSIDIARY RISK: 6.1
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
EMS: NOT AVAILABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
GENERAL INFORMATION:
DOT REGULATED MARINE POLLUTANT. IMDG REGULATED MARINE POLLUTANT.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
DECAFLUOROPENTANE (CAS 138495-42-8):
1.0% ONE-TIME EXPORT NOTIFICATION ONLY.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
TETRACHLOROETHYLENE (CAS 127-18-4)
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
TETRACHLOROETHYLENE (CAS 127-18-4)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
TETRACHLOROETHYLENE (CAS 127-18-4) 100 LBS
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5) 1000 LBS
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
TETRACHLOROETHYLENE (CAS 127-18-4)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SECTION 311/312 HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: NO
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
US STATE REGULATIONS:
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
CARBON DIOXIDE (CAS 124-38-9)
TETRACHLOROETHYLENE (CAS 127-18-4)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
CARBON DIOXIDE (CAS 124-38-9)
TETRACHLOROETHYLENE (CAS 127-18-4)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
TETRACHLOROETHYLENE (CAS 127-18-4)
CARBON DIOXIDE (CAS 124-38-9)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
US. RHODE ISLAND RTK:
TETRACHLOROETHYLENE (CAS 127-18-4)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/CARCINOGENIC SUBSTANCE
TETRACHLOROETHYLENE (CAS 127-18-4) LISTED: APRIL 1, 1988
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 7.8%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS REGULATED AS A GENERAL PURPOSE DEGREASER (AEROSOL). THIS
PRODUCT IS NOT COMPLIANT TO BE SOLD FOR USE IN CALIFORNIA, CONNECTICUT,
DELAWARE, THE DISTRICT OF COLUMBIA, ILLINOIS, INDIANA, MAINE, MARYLAND,
MASSACHUSETTS, MICHIGAN, NEW JERSEY, NEW YORK, AND RHODE ISLAND. THIS
PRODUCT IS COMPLIANT IN ALL OTHER STATES.
VOC CONTENT (CA): 9.8%
VOC CONTENT (OTC): 7.8%
INTERNATIONAL INVENTORIES:
COUNTRY(S) INVENTORY NAME ON INVENTORY
OR REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES YES
(AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES YES
IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING COMMERCIAL NO
CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL YES
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND YES
CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 05-19-2014
PREPARED BY: ALLISON CHO
VERSION #: 01
FURTHER INFORMATION: CRC # 894A
HMIS(R*) RATINGS:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY
CRC TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND
DIRECTIONS ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION
CONTAINED ON THIS (M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY
PROFESSIONAL, OR CRC INDUSTRIES.
MATERIAL NAME: HEAVY DUTY DEGREASER
1750
SDS US