| Common Name: | HARDHT LSPR 6PK STRIPE YELLOW STRIPING, 2348838 |
| Manufacturer: | RUST-OLEUM |
| MSDS Revision Date: | 9/23/2009 |
| Grainger Item Number(s): | 1F764, 6A380, 6A938, 6A939, 6H084 |
| Manufacturer Model Number(s): |
MSDS Table of Contents
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MATERIAL SAFETY DATA SHEET
24 HOUR ASSISTANCE:
1-847-367-7700
RUST-OLEUM CORP.
WWW.RUSTOLEUM.COM
| SECTION 1 - CHEMICAL PRODUCT / COMPANY INFORMATION |  |
PRODUCT NAME: HARDHT LSPR 6PK STRIPE YELLOW STRIPING
IDENTIFICATION NUMBER: 2348838
REVISION DATE: 09/23/2009
PRODUCT USE/CLASS: STRIPING PAINT/AEROSOLS
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
| SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NUMBER WEIGHT % LESS THAN
LIQUEFIED PETROLEUM GAS 68476-86-8 25.0
ALIPHATIC HYDROCARBON 64742-89-8 10.0
TOLUENE 108-88-3 10.0
NAPHTHA 8032-32-4 10.0
ACETONE 67-64-1 5.0
TITANIUM DIOXIDE 13463-67-7 5.0
MINERAL SPIRITS 64742-88-7 5.0
XYLENE 1330-20-7 5.0
SOLVENT NAPTHA, LIGHT AROMATIC 64742-95-6 5.0
1,2,4-TRIMETHYLBENZENE 95-63-6 5.0
ETHYLBENZENE 100-41-4 1.0
QUARTZ (CRYSTALLINE SILICA) 14808-60-7 1.0
METHYL ETHYL KETOXIME 96-29-7 0.1
CHEMICAL NAME ACGIH ACGIH OSHA OSHA PEL
TLV-TWA TLV-STEL PEL-TWA CEILING
LIQUEFIED PETROLEUM GAS N.E. N.E. N.E. N.E.
ALIPHATIC HYDROCARBON N.E. N.E. 300 PPM N.E.
TOLUENE 20 PPM N.E. 200 PPM 300 PPM
NAPHTHA N.E. N.E. N.E. N.E.
ACETONE 500 PPM 750 PPM 1000 PPM N.E.
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
(TOTAL DUST)
MINERAL SPIRITS 100 PPM N.E. 100 PPM N.E.
XYLENE 100 PPM 150 PPM 100 PPM N.E.
SOLVENT NAPTHA, LIGHT N.E. N.E. N.E. N.E.
AROMATIC
1,2,4-TRIMETHYLBENZENE 25 PPM N.E. N.E. N.E.
ETHYLBENZENE 100 PPM 125 PPM 100 PPM N.E.
QUARTZ (CRYSTALLINE SILICA) 0.025 MG/M3 N.E. 2.4 MPPCF N.E.
(RESPIRABLE)
METHYL ETHYL KETOXIME N.E. N.E. N.E. N.E.
| SECTION 3 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
CONTENTS UNDER PRESSURE. HARMFUL IF INHALED. MAY AFFECT THE BRAIN OR NERVOUS
SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. VAPORS MAY CAUSE FLASH FIRE OR
EXPLOSION. HARMFUL IF SWALLOWED. EXTREMELY FLAMMABLE LIQUID AND VAPOR.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION. SUBSTANCE MAY CAUSE
SLIGHT SKIN IRRITATION.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND
LUNGS. AVOID BREATHING VAPORS OR MISTS. HIGH GAS, VAPOR, MIST OR DUST
CONCENTRATIONS MAY BE HARMFUL IF INHALED. HARMFUL IF INHALED.
EFFECTS OF OVEREXPOSURE - INGESTION:
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE. SUBSTANCE
MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
CONTAINS TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP
2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY IARC. SIGNIFICANT EXPOSURE IS NOT
ANTICIPATED DURING BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS
ON DURATION AND LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES
OR SPRAY MIST AND THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE
FORMULA.
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B).
MAY CAUSE CENTRAL NERVOUS SYSTEM DISORDER (E.G., NARCOSIS INVOLVING A LOSS
OF COORDINATION, WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION)
AND/OR DAMAGE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER
ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS
REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE, HAVE
INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE.
OVEREXPOSURE TO TOLUENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER
ABNORMALITIES, KIDNEY, LUNG AND SPLEEN DAMAGE. EFFECTS IN HUMANS HAVE
INCLUDED LIVER AND CARDIAC ABNORMALITIES.
CONTAINS CRYSTALLINE SILICA AS SILICON DIOXIDE. EXCESSIVE INHALATION OF
RESPIRABLE CRYSTALLINE SILICA DUST MAY CAUSE LUNG DISEASE, SILICOSIS OR LUNG
CANCER. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH OR TROWEL
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON THE DURATION AND
LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES, MECHANICAL
ABRASION OR SPRAY MIST AND ACTUAL CONCENTRATION OF CRYSTALLINE SILICA IN THE
FORMULA, CRYSTALLINE SILICA IS LISTED AS GROUP 1 "CARCINOGENIC TO HUMANS" BY
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC), AND GROUP 2
"REASONABLY ANTICIPATED TO BE A CARCINOGEN" BY THE NATIONAL TOXICOLOGY
PROGRAM (NTP).
PRIMARY ROUTE(S) OF ENTRY:
SKIN CONTACT, SKIN ABSORPTION, INHALATION, INGESTION, EYE CONTACT
| SECTION 4 - FIRST AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR KEEPING
EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR
PERSISTS.
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE
IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: -156 F (SETAFLASH)
LOWER EXPLOSIVE LIMIT: 0.7%
UPPER EXPLOSIVE LIMIT: 12.8%
EXTINGUISHING MEDIA:
FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
WATER SPRAY MAY BE INEFFECTIVE. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS CAN
TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. FLASH POINT IS LESS THAN
20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR!
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. PERFORATION OF THE PRESSURIZED CONTAINER MAY CAUSE
BURSTING OF THE CAN.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND
FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS. REMOVE ALL SOURCES
OF IGNITION, VENTILATE AREA AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING
TOOLS.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING
VAPOR OR MIST. USE ONLY IN A WELL-VENTILATED AREA. WASH HANDS BEFORE EATING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. DO NOT STORE ABOVE 120 DEG. F. STORE LARGE QUANTITIES
IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS I FLAMMABLE
LIQUIDS. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE ABOVE
120 DEG. F.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR
OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS. USE EXPLOSION-PROOF VENTILATION EQUIPMENT.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH AN
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE
LIMITS.
PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR IN ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING RANGE: -34 - 415 F
VAPOR DENSITY: HEAVIER THAN AIR
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
APPEARANCE: AEROSOLIZED MIST
EVAPORATION RATE: FASTER THAN ETHER
SOLUBILITY IN H2O: SLIGHT
FREEZE POINT: N.D.
SPECIFIC GRAVITY: 0.942
VAPOR PRESSURE: N.D.
pH: N.A.
PHYSICAL STATE: LIQUID
(SEE SECTION 16 FOR ABBREVIATION LEGEND)
| SECTION 10 - STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F. AVOID ALL POSSIBLE SOURCES OF IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES. BY
OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
PRODUCT LD50: N.D.
PRODUCT LC50: N.D.
CHEMICAL NAME LD50 LC50
LIQUEFIED PETROLEUM GAS N.E. N.E.
ALIPHATIC HYDROCARBON >5000 MG/KG N.E.
(RAT, ORAL)
TOLUENE 636 MG/KG >26700 PPM
(RAT, ORAL) (RAT, INHALATION, 1 HR)
NAPHTHA >5000 MG/KG N.E.
(RAT, ORAL)
ACETONE 5800 MG/KG (RAT) 50100 MG/M3 (RAT, 8 HR)
TITANIUM DIOXIDE >7500 MG/KG N.E.
(RAT, ORAL)
MINERAL SPIRITS >8 MG/KG >1400 PPM
(RAT, ORAL) (RAT, INHALATION, 4 HR)
XYLENE 4300 MG/KG 5000 PPM
(RAT, ORAL) (RAT, INHALATION, 4 HR)
SOLVENT NAPTHA, LIGHT AROMATIC 4700 MG/KG 3670 MG/KG
(RAT, ORAL) (RAT, INHALATION)
1,2,4-TRIMETHYLBENZENE N.E. 18000 MG/M3 (RAT, 4 HR)
ETHYLBENZENE 3500 MG/KG N.E.
(RAT, ORAL)
QUARTZ (CRYSTALLINE SILICA) N.E. N.E.
METHYL ETHYL KETOXIME 3680 MG/KG (RAT) >4.8 MG/L (RAT)
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| SECTION 13 - DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR SEWER SYSTEMS.
| SECTION 14 - TRANSPORTATION INFORMATION | |
DOT PROPER SHIPPING NAME: AEROSOLS
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: 2.1
DOT UN/NA NUMBER: UN1950
PACKING GROUP: N.A.
HAZARD SUBCLASS: N.A.
RESP. GUIDE PAGE: 126
| SECTION 15 - REGULATORY INFORMATION | |
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD, PRESSURIZED
GAS HAZARD
SARA SECTION 313:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS NUMBER
TOLUENE 108-88-3
XYLENE 1330-20-7
1,2,4-TRIMETHYLBENZENE 95-63-6
ETHYLBENZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE
UNITED STATES:
IT IS THE POLICY OF RUST-OLEUM CORPORATION TO USE ONLY TSCA COMPLIANT
MATERIALS IN ITS PRODUCTS.
U.S. STATE REGULATIONS: AS FOLLOWS
NEW JERSEY RIGHT-TO-KNOW:
THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE
COMPONENTS IN THIS PRODUCT.
CHEMICAL NAME CAS NUMBER
CALCIUM CARBONATE 1317-65-3
MODIFIED ALKYD PROPRIETARY
PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT
GREATER THAN 3%.
CHEMICAL NAME CAS NUMBER
CALCIUM CARBONATE 1317-65-3
MODIFIED ALKYD PROPRIETARY
CALIFORNIA PROPOSITION 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN BY THE STATE OF CALIFORNIA TO
CAUSE CANCER.
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS:
AB5
D2A
D2B
| SECTION 16 - OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 4
REACTIVITY 0
PERSONAL PROTECTION X
REASON FOR REVISION: REGULATORY UPDATE
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS MATERIAL SAFETY DATA SHEET. HOWEVER, BECAUSE THE
CONDITIONS OF HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR
CONTROL, WE ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR
PROPERTY DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM
CORPORATION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY
OR RELIABILITY OF THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS
MAY PRESENT UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION
AND RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.