TOSCO INDUSTRIAL -- LOW SULFUR NO 2 DIESEL  -- 9140-00N074090
<pre>=====================  Product Identification  =====================

Product ID:LOW SULFUR NO 2 DIESEL
MSDS Date:03/07/1996
FSC:9140
NIIN:00N074090
=== Responsible Party ===
Company Name:TOSCO INDUSTRIAL
Address:2 UNION SQUARE, 601 UNION ST, SUITE 2500
City:SEATTLE
State:WA
ZIP:98101
Country:US
Info Phone Num:206-442-7000
Emergency Phone Num:510-228-1220;800-424-9300(CHEMTREC)
CAGE:JO407
=== Contractor Identification ===
Company Name:TOSCO INDUSTRIAL
Address:2 UNION SQUARE, 601 UNION ST, SUITE 2500
Box:City:SEATTLE
State:WA
ZIP:98101
Country:US
Phone:206-442-7000
CAGE:JO407
Company Name:TOSCO REFINING CO
Address:2300 CLAYTON RD
Box:City:CONCORD
State:CA
ZIP:94520
Country:US
Phone:800-424-9300 (CHEMTREC)
CAGE:TXSCX

=============  Composition/Information on Ingredients  =============

Ingred Name:DIESEL FUELS; (NO. 2 DIESEL FUEL) %: 99.8-100
CAS:68334-30-5
RTECS #:HZ1800000
Fraction by Wt: <100%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SULFUR DIOXIDE (SARA 302)
CAS:7446-09-5
RTECS #:WS4550000
Fraction by Wt: >0.5%
OSHA PEL:5 PPM
ACGIH TLV:2 PPM/5 STEL

Ingred Name:NON-HAZARDOUS INGREDIENTS
Fraction by Wt: <1.0%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUP DAT: PROTECT RESPONDING PERSONNEL. KEEP MATERIAL OUT OF
    PUBLIC SEWERS AND WATERWAYS.
RTECS #:9999999ZZ

Ingred Name:EFTS OF OVEREXP: PRODS OF SIMILAR COMPOSITION HAVE PRDCED
    SKIN CANCER IN LAB ANIMALS. EYE: SLIGHTLY IRRITATING. (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5: EXPOS TO VAPS, FUMES/MISTS MAY CAUSE IRRIT. INHAL:
    MAY CAUSE RESP TRACT IRRIT. CNS EFTS ARE SIMILAR TO (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6: THOSE LISTED UNDER INGEST. DEGENERATIVE CHANGES IN
    LIVER, KIDNEYS & BONE MARROW MAY OCCUR W/PRLNG HIGH (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: CONCS. RPTD/PRLNG EXPOS MAY CAUSE BEHAVIORAL
    CHANGES.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: FROM EYEBALL TO ENSURE THORO RINSING. GET
    MED ATTN IF IRRIT RSLTS. INHAL: REMOVE FROM SOURCE OF (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: EXPOS. IF NOT BRTHG ENSURE OPEN AIRWAY & GIVE ARTF
    RESP/CPR AS NEEDED. ADMIN OXYGEN IF AVAIL. GET IMMED MED ATTN.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: STAY UPWIND; KEEP OUT OF LOW AREAS. USE REC
    PERS PROT EQUIP. KEEP UNNEC & UNPROT PERS AWAY; ISOLATE (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: AREA & DENY ENTRY. SHUT OFF IGNIT SOURCES; NO
    FLARES, SMKNG, OPEN FLAMES/VEHICLES IN HAZ AREA. VAPS MAY (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: BE SUPPRESSED W/FIRE FOAM BLANKET. CONTAIN SPILL
    FAR DOWNSTREAM BY DIKING. TAKE UP SML SPILLS W/SAND/ (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: OTHER COMPATIBLE ABSORB. ANY
    SPILL/RELEASE/SUBSTANTIAL THREAT OF RELEASE, OF THIS MATL TO SURF
    WATER, (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: SUFFICIENT TO CAUSE VISIBLE SHEEN ON WATER MUST BE
    REPORTED IMMED TO NATL RESPONSE CTR (800/424-8802), (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: AS REQUIRED BY U.S. FED LAW. ALSO NOTIFY COAST
    GUARD & APPROP STATE & LOC REGULATORY AGENCIES.
RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH: AS HAZ WASTE UNDER SOME STATE/LOC REGS.
    CHEM ADDNS, PROCESSING/OTHERWISE ALTERING THIS MATL (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: MAY MAKE THE WASTE MANAGEMENT INFO IN THIS MSDS
    INCOMPLETE, INACCURATE OR OTHERWISE INAPPROPRIATE. (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
    FEDERAL REGULATIONS .
RTECS #:9999999ZZ

Ingred Name:OTHER PREC: BY MOUTH. DO NOT USE FOR CLEANING, PRESS
    APPLIANCE FUEL/ANY OTHER USE EXCEPT AS MOTOR FUEL. KEEP OUT(ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: OF REACH OF CHILDREN. EMPTY CONTRS MAY CONTAIN
    TOXS, FLAM/COMBUST/EXPLO RESIDUE/VAPS. DO NOT CUT, GRIND,(ING 22)
RTECS #:9999999ZZ

Ingred Name:ING 21: DRILL, WELD, REUSE/DISPOSE CONTRS UNLESS ADEQ PREC
    ARE TAKEN AGAINST THESE HAZARDS. AVOID SKIN & EYE CONTACT.
RTECS #:9999999ZZ

Ingred Name:OTHER PROT EQUIP: SPLASH PROT. WASH WORK CLTHG REGULARLY.
    REMOVE CONTAM CLTHG. DO NOT WEAR CONTAM CLTHG NEAR (ING 24)
RTECS #:9999999ZZ

Ingred Name:ING 23: SOURCES OF IGNIT SUCH AS SPARKS/OPEN FLAMES.
    SOLVENT BARRIER CREAMS MAY BE USED TO SUPPLEMENT IMPERVIOUS GLOVES.
RTECS #:9999999ZZ

Ingred Name:HYGIENE PRACT: REMOVE CONTAMINATED CLOTHING & CLEAN BEFORE
    REUSE. SHOWER AFTER WORK USING SOAP AND WATER.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: DANGER! HARMFUL/FATAL IF
    SWALLOWED. ASPIR HAZ IF SWALLOWED; CAN ENTER LUNGS & CAUSE DMG.
    VAPS MAY BE HARMFUL. MAY BE IRRIT TO SKIN, EYES & RESP TRACT. POSS
    SKIN CANCER HAZ. CONTAINS MATL WHICH  MAY CAUSE CANCER BASED ON
    ANIMAL DATA. INGEST: ASPIR INTO LUNGS MAY CAUSE PNEUMIT. MAY CAUSE
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: GI DISTURBS. SYMPS MAY INCL IRRIT,
    NAUS, VOMIT & DIARR. MAY CAUSE HARMFUL CNS EFTS INCL EXCITATION,
    EUPHORIA, HDCH, DIZZ, DROW, BLURRED VISION, FATG, TREMORS, CONVLS,
    LOSS OF CONSCIOUSNESS,  COMA, RESP ARREST & DEATH. SKIN: MOD IRRIT.
    RPTD/PRLNG CONT MAY RSLT IN DERM & POSS SECONDARY INFECTION. (ING
    5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INGEST: DO NOT INDUCE VOMIT BECAUSE OF DANGER OF ASPIR INTO
    LUNGS. GET IMMED MED ATTN. IF SPONT VOMIT OCCURS, MONITOR BRTHG FOR
    DFCLTY. SKIN: REMOVE CONTAM CLTHG IMMED. WASH AREA THORO W/SOAP &
    WATER.  GET MED ATTN IF IRRIT PERSISTS. HIGH PRESS INJECTIONS ARE
    SERIOUS MED EMER REQUIRING IMMED MED ATTN. EYE: FLUSH IMMED W/LGE
    AMTS OF WATER FOR AT LEAST 15 MIN. EYELIDS SHOULD BE HELD AWAY (ING
    9)

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:>130F,>54C
Lower Limits:0.3%
Upper Limits:10%
Extinguishing Media:USE DRY CHEMICAL, ALL PURPOSE AFPF, ALCOHOL FOAM OR
    CARBON DIOXIDE TO EXTINGUISH FIRE.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
    WATER MAY BE INEFFECTIVE FOR EXTING FIRE BUT MAY BE USED TO COOL
    FIRE-IMPINGED/EXPANDED CONTRS & (SUP DAT)
Unusual Fire/Explosion Hazard:CAUTION: COMBUSTIBLE LIQUID & VAPORS.
    DANGEROUS WHEN EXPOSED TO HEAT/FLAMES. RUNOFF TO SEWER MAY CAUSE
    FIRE/EXPLOSION HAZARD. CONTAINERS MAY EXPLODE IF HEATED.

==================  Accidental Release Measures  ==================

Spill Release Procedures:IF YOUR FACILITY HAS A HAZ MATLS EMER SPILL
    PLAN, ACTIVATE ITS PROC. FOR TRANSPORTATION/OTHER LGE SPILLS,
    FOLLOW U.S. DEPT. OF TRANSPORTATION "EMER ACTION GUIDE #27". TAKE
    IMMED STEPS TO STOP & CONTAI N SPILL IF THERE IS NO RISK TO PERS
    SFTY. (ING 11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE DIESEL ONLY IN NFPA APPRVD,
    CLEARLY LABELED CONTRS THAT ARE TIGHTLY CLSD. NEVER STORE IN
    GLASS/UNAPPROVED PLASTIC CONTRS.
Other Precautions:STOR LOCATION MUST BE COOL, DRY, ISOLATED, WELL-VENTD
    & AWAY FROM HEAT, SOURCES OF IGNIT & INCOMPATIBLE MATLS. USE
    GROUNDING WIRES & EQUIP DURING PROD TRANSFER TO REDUCE POSS OF
    STATIC SPK CAUSED FIRE /EXPLO. DO NOT SIPHON THIS PROD (ING 20)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF VENTILATION IS NOT ADEQUATE TO REDUCE
    EXPOSURE BELOW PERMISSIBLE LIMITS, OR IF IRRITATION IS EXPERIENCED,
    NIOSH APPROVED RESPIRATORY PROTECTION SHOULD BE WORN.
Ventilation:USE ADEQUATE VENTILATION WHERE POSSIBLE.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
    WEAR PROT CLTHG INCL COVERALLS/LAB APRONS AS NEEDED FOR POSS (ING
    23)
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS
    BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. (ING
    25)
Supplemental Safety and Health
APPEAR/ODOR: DIESEL IS DYED RED. FIRE FIGHT PROC: STRUCTURES. WATER MAY
    BE USED TO PROTECT PERS & KEEP MATL AWAY FROM SOURCES OF IGNIT. IF
    LEAK/SPILL HAS NOT IGNITED, VENT AREA & USE WATER SPRAY TO DI
    SPERSE GAS/VAP & TO PROTECT PERS ATTEMPTING TO STOP LEAK. FOAM
    BLANKETS MAY ALSO BE USED TO REDUCE VAPS & (ING 4)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:>320F,>160C
Vapor Pres:0.40 @ 68F
Vapor Density:>3.0
Spec Gravity:0.81-0.88
pH:NEUT
Evaporation Rate &amp; Reference:<1 (WATER=1)
Appearance and Odor:HIGHWAY DIESEL IS STRAW COLORED LIQ, W/HYDROCARBON
    ODOR; NON-HIGHWAY (SUP DAT)
Percent Volatiles by Volume:NEGLIG

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BURNING MATL WILL EMIT IRRIT & TOX
    SUBSTANCES. COMBUST MAY PRDCE CARBON MONOXIDE & DIOXIDE & REACTIVE
    HYDROCARBONS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:THIS MATL IN ITS ORIGINAL FORMULATION, WHEN
    DISCARDED/DISP OF, IS NOT SPECIFICALLY LISTED AS HAZ WASTE,
    HOWEVER, IT MAY BE CONSIDERED A CHARACTERISTICALLY HAZ IGNIT WASTE
    UNDER FED REGS WHEN IN FREE L IQ FORM. ALSO, THIS MATL MAY BE
    DEFINED(ING 17)

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